有机化学（下）复习题 - 完成反应式

有机化学II总复习（一）——完成反应式

2C2H5CHCOOHH+( )OH

HOOCCH=CHCHCOOH( )COOH

OCOOHHOOC( ) COOH( )COOH

C6H5COONa + CH2CHCH2Br( )

CO2Na+BrCH2Br( )CH3CH2CH2COOH+Br2P( )OH-H( )2OHCOOHClPb(OAc)4, I2HCCl( )RONa4OOC2H5OH( )C2H5OHH+( )OOO2NCCl+HNNaOHH2O( ) CH3OO+CH3NH2( )

CH3CHH5OH3OC2OC( )2H5ONa

( )

1

NHOLiAlH4H2O( )

( )O(1)LiAlH4O(2)H3O+COCl

H2, Pd/BaSO4( )硫喹啉ClOCH+3CH=CHCH2CH2COC2H5NaHC( )2H5OHCOOCH3(CH2)12NaH+COOCH二 甲 苯( )3COOC2H5(CH3CH2)2CdCOCl( )

CH3CH2COCl(CH3)2CuLiether( )OO+C2H5MgBr乙醚H+/H2O( )CNC6H5MgBrH+/H2O( )COOC2H5NaOC2H5( )CH2COCH2CH3COOC2H5+CH3COOC2H5C2H5ONa( )OCOOC2H52C2H5ONa( )COOC2H5CHNaOCH33CH2NO2+CH2=CHCOCH3( )

OH-H+H( )2O

2

OCOOC2H5NaH+COOC( )2H5C6H6

CH+(C2H5O)2COC2H5ONa2CN甲 苯( )OCH3+HCOOC2H5NaHH+ether( ) CHCH3CH2CH2COOC2H5LDA,THF( )3CH2I( ) NCCH2COOC2HC52H5ONaCH3COCH=CHPh( )

CHO+CH3COCH3OH( )ClCH2CO2C2H5NaOC2H( )(1)OH /H2O5(2)H+/( )O+ClCH2COOCKOC(CH2H53)3t BuOH( )

CHO-+BrCH2COOC2H51.Zn/C6H61.OH/H2O2.H+2.H+/( )

OOCHNaOC2H55OC(CH2)4COC2H5NaOC2H5( )(1)(1)OH- /H2O2(2)BrCH( )25(2)H+( )O+对 甲 苯 磺 酸(1)ClCH2CH=CH2甲 苯( )(2)H3O+( )NH ONHKOH(s)( )PhCH2Br( )H2OOH-( )O

H3COHCCBr2 / OHPhNH( )2

ONHBr2/OH( )O

3

NO2BrZn/OH( )H+( ) C6H5CONH2P2O5( )

CH3OHONaN3CH2CCl( )COH(1)SOCl22Ag2O(2)CH( )2N2H( )2OO2NCH2NHCOCH3H2/Pt( )O+CH3CH2NH2H2/Pt压力，( ) HNHCH3HCHO/H+( )OHOHHNO2CH( )2NH2

NaNO2HCl( )OHNH2

CH3COOCHCH2CH(CH3)2500 C。( )C(CH3)3HDCH3CCCH3COO( )CH3CHH2BrCH3CH2CH2CHN(CH3)3OH ( )CH3CH3CH3( )+N(CH3)3OH

( )

(1)LiAlH4(2)H( )2O

500 C。( )

4

CH2CH3N(CH3)2CH3CH3CH3INH过量Ag2OH2OH2O2( )。200 C( )

( )( )

CH3NNCl++HOClNaOHH2O( )CH3CH3CH3OC2H5( )

CO2CH3H..CH3C2H5CH3O2CCO2CH3( )( )( )CO2CH3

+( )+

CH2N2+CH3OCOCCCOOCH3( )

N++CH2=CHCOOCH3O( )OC2H5( )HO( )CH2CH=CH2( )

( )

( )CH3OCH3+CH3OOCCCCOOCH3

5

+HCHOHCl/ZnCl2( )S COOHBrCH3CO2HS+225 Co( )

H2SOS25 C。4( )N+CH3I( )NH

CH3(1)NaNH2N(2)PhCOCl( )CH3 HNO3( )NH2SO4

CH3C6H5LiOCHO( )H3O+N ( )ClClCH3ONaCH( )3OH,NRLi( )CH2=CHCN( )NCH3NaNO2,HClCuBr( )CH2(COOC2H5)2H3+ONNH2C( )2H5ONaNCCHH5OCHO2COOC2CH( )3COONH4

O+CCHNaNH23( )NCH3

6

CH2OHHHOOH+3PhNHNH2OHCH2OHCH2OCH3OCH3OCH2OCH3OOCH3HAc( )

H3O+( )+( )CHO3OOCH3CH3OOCH3CH2OHOHOHAg(NH3)2+( )HOHCH2OHCH2OHOOHOHOHNaBH4( )OH

CH3COCH3HCl( )

7

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