有机综合练习卷1

有机综合练习卷1

完成下列反应，写出主要产物： 1.

OHOOOHΔ

2.

OHCHOH2OHOOHHOMeOHdry HCl

3.

HNO3NH2SO4

O4.

ΔN+O

5. EtHCl2/H2O（写出产物的费歇尔投影式）

6.

(1) NaNH2N(2) CH3I

7.

H2/PtCOOCH3 H2SO48.

Sroom temperature

9. C6H5H3CHCH3(1) B2H6(2) H2O2/OH-（写出产物的费歇尔投影式）

10.

NH2+OAs2O5H2SO4

11.

O+OOAlCl3Zn/HgHCl

12.

COO-HBrH3COH-Ag2O（标明产物的构型）

13.

BrCH3BrOH-EtOHH2OHgSO4/H2SO4

14. NO2BrZnOH-H+

15. OOONH2CH3CH3COClH2Pt

16.

PhCO3HO

17.

ClOH-

18. O+CH3CH2CH2NH219. CHOHOHHOH(1) HCNHOH(2)H+(3)Na+HgCH2OH

20. ONaBH4Cl

21.

EtCO2C2H5OPh+CO2C2H5H2NNH222. HMeNH2Br2EtOOH-

23.

OOH-N2Cl

H2PtOH-

24.

NaNH3 ( l )

25.

OH+CH3COOHCH2OH26.

ΔNOH

27.

OOHClH2O28.

OHOOH29.

OCl(1)CH2N2(2)Ag2O/H2O

30.

BrBrNaCNNMeOH

31.

CHCl3OH-

32.

NaNO2OHNHHCl2

H+

H+

33.

OO+OOΔ

34.

OPhONHCOOH+H2NOOPhDCCH2/Ni

Li/ NH3(l)35.

ClCH2CH3ClNaNH2

ΔCl36.

HN

37.

OΔ

38.

(1)ZnO+BrCH2CO2C2H5(2)H+OH+

39.

O+OΔHCl

40.

OPh3P=CHCH2NMe2

41.

PhOHCH3NH2（写出费歇尔投影式）

42.

H2NCH2COOH+OH43.

H2SO4OH

44.

OCHOOH-1mol+2molCHOO

45.

COOH(1) NaNO2/HClNH2(2)Δ

46.

1molHOHOHCO2OHHO+2molOHOH47.

ONHH2O2NPt48.

(1) NaNH2N(2) PhCOCl

(1) n-C4H9Li/CH3CH2Br(2) H3O+

H+

(1) NaNO2/H2SO4(2) H3O+/Δ

有机综合练习卷1答案

（仅供参考） ．．．．

完成下列反应，写出主要产物：

1.

O

2.

OHCH2OHHOOOHOCH33. NO2N4.

NCO2CH35.

C2H5ClHCH33HOCH6.

N

7.

CO2CH3

OHOHCOO OHC

NNO2

HOCCH32H5H3CClH

8.

HO3SS

CH3PhHHPhCH39.

CH3HPhHOHCH3

10.

N

11.

OCOOHCOOH

12.

CO2-HH3COH

O13.

14.

BrHHNNBrH2NBrBrNH2

15. OCO2CH3HNOHNOHOCO2CH3

16.

OO

17. HO18.

NH

19. CHOHOHHOHHOHHOHCH2OH20. OHCl

21.

OEtNHPhONHO22. H3CNH2CH2H5

HOCHOOHHOHHOHHOHCH2OH

HO

23.

O

24.

HHCH3

25.

OHOO

26.

N 27. OOH28.

OO29.

OHO30. CNBrN

OO

31.

ClCl

32.

O

33. OHOOHO

OOPh34.

OPhONHOHNH2NHNOOOH

35.

HHCH3

36. N 37.

OH

38.

OHCO2C2H5

OOCO2C2H5

39.

OOHOOH

40.

N

41.

CH3HOPhHNHCH3CH3

42.

ONEtCOOH

43.

44.

OO

45. Cl

46.

PhOOOHOOO47.

OH2NNH48.

NPhO

NH2

HO

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